Beneficial influence of nanocarbon on the aryliminopyridylnickel chloride catalyzed ethylene polymerization

A series of 1-aryliminoethylpyridine ligands (L1―L3) was synthesized by condensation of 2-acetylpyridine with 1-aminonaphthalene, 2-aminoanthracene or 1-aminopyrene, respectively. Reaction with nickel dichloride afforded the corresponding nickel (II) chloride complexes (Ni1–Ni3). All compounds were fully characterized and the molecular structures of Ni1 and Ni3 are reported. Upon activation with methylaluminoxane (MAO), all nickel complexes exhibit high activities for ethylene polymerization, producing waxes of low molecular weight and narrow polydispersity. The presence of multi-walled carbon nanotubes (MWCNTs) or few layer graphene (FLG) in the catalytic medium can lead to an increase of productivity associated to a modification of the polymer structure

Observation of recoil-induced resonances and electromagnetically induced absorption of cold atoms in diffuse light

In this paper we report an experiment on the observation of the recoil-induced resonances (RIR) and electromagnetically induced absorption (EIA) of cold Rb87 atoms in diffuse light. The pump light of the RIR and the EIA comes from the diffuse light in an integrating sphere, which also serves the cooling light. The probe light beam is a weak laser split from the cooling laser in order to keep the cooling and probe lasers correlated. We measured the RIR and the EIA signal varying with the detuning of the diffuse laser light, and also measured the temperature of the cold atoms at the different detunings. The mechanism of RIR and EIA in the configuration with diffuse-light pumping and laser probing is discussed, and the difference of nonlinear spectra of cold atoms between in diffuse-light cooling system and in optical molasses as well as in a magneto-optical trap (MOT) are studied.Comment: 9 pages, 6 figure

The edge engineering of topological Bi(111) bilayer

A topological insulator is a novel quantum state, characterized by symmetry-protected non-trivial edge/surface states. Our first-principle simulations show the significant effects of the chemical decoration on edge states of topological Bi(111) bilayer nanoribbon, which remove the trivial edge state and recover the Dirac linear dispersion of topological edge state. By comparing the edge states with and without chemical decoration, the Bi(111) bilayer nanoribbon offers a simple system for assessing conductance fluctuation of edge states. The chemical decoration can also modify the penetration depth and the spin texture of edge states. A low-energy effective model is proposed to explain the distinctive spin texture of Bi(111) bilayer nanoribbon, which breaks the spin-momentum orthogonality along the armchair edge.Comment: 5 pages, 5 figure

Nuclear geometry effect and transport coefficient in semi-inclusive lepton-production of hadrons off nuclei

Hadron production in semi-inclusive deep-inelastic scattering of leptons from nuclei is an ideal tool to determine and constrain the transport coefficient in cold nuclear matter. The leading-order computations for hadron multiplicity ratios are performed by means of the SW quenching weights and the analytic parameterizations of quenching weights based on BDMPS formalism. The theoretical results are compared to the HERMES positively charged pions production data with the quarks hadronization occurring outside the nucleus. With considering the nuclear geometry effect on hadron production, our predictions are in good agreement with the experimental measurements. The extracted transport parameter from the global fit is shown to be $\hat{q} = 0.74\pm0.03 GeV^2/fm$ for the SW quenching weight without the finite energy corrections. As for the analytic parameterization of BDMPS quenching weight without the quark energy E dependence, the computed transport coefficient is $\hat{q} = 0.20\pm0.02 GeV^2/fm$. It is found that the nuclear geometry effect has a significant impact on the transport coefficient in cold nuclear matter. It is necessary to consider the detailed nuclear geometry in studying the semi-inclusive hadron production in deep inelastic scattering on nuclear targets.Comment: 14 pages, 3 figures. arXiv admin note: text overlap with arXiv:1310.569

Dichloropalladium complexes ligated by 4,5-bis(arylimino)pyrenylidenes: Synthesis, characterization, and catalytic behavior towards Heck-reaction

A series of 4,5-bis(arylimino)pyrenylidenylpalladium(II) chloride complexes (C1–C4) were synthesized and characterized by FT-IR and NMR spectroscopy, elemental analysis as well as by single crystal X-ray diffraction for the representative complexes C1 and C3, which revealed a square planar geometry at the palladium center. All palladium complexes exhibited high activity for the Heck cross-coupling reaction, which were effective when conducted in various solvents. Furthermore, the in-situ mixture of palladium dichloride and the ligand (L1) provided an effective catalytic system for the Heck-reaction

Exact treatment of magnetism-driven ferroelectricity in the one-dimensional compass model

We consider a class of one-dimensional compass models with antisymmetric Dzyaloshinskii-Moriya exchange interaction in an external magnetic field. Based on the exact solution derived by means of Jordan-Wigner transformation, we study the excitation gap, spin correlations, ground-state degeneracy, and critical properties at phase transitions. The phase diagram at finite electric and magnetic field consists of three phases: ferromagnetic, canted antiferromagnetic, and chiral. Dzyaloshinskii-Moriya interaction induces an electrical polarization in the ground state of the chiral phase, where the nonlocal string order and special features of entanglement spectra arise, while strong chiral correlations emerge at finite temperature in the other phases and are controlled by a gap between the nonchiral ground state and the chiral excitations. We further show that the magnetoelectric effects in all phases disappear above a typical temperature corresponding to the total bandwidth of the effective fermionic model. To this end we explore the entropy, specific heat, magnetization, electric polarization, and the magnetoelectric tensor at finite temperature. We identify rather peculiar specific-heat and polarization behavior of the compass model which follows from highly frustrated interactions.Comment: 15 pages, 15 figures, Slight change comparing with the published versio